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By NASA
5 min read
Atomic Layer Processing Coating Techniques Enable Missions to See Further into the Ultraviolet
Astrophysics observations at ultraviolet (UV) wavelengths often probe the most dynamic aspects of the universe. However, the high energy of ultraviolet photons means that their interaction with the materials that make up an observing instrument are less efficient, resulting in low overall throughput. New approaches in the development of thin film coatings are addressing this shortcoming by engineering the coatings of instrument structures at the atomic scale.
Researchers at the NASA Jet Propulsion Laboratory (JPL) are employing atomic layer deposition (ALD) and atomic layer etching (ALE) to enable new coating technologies for instruments measuring ultraviolet light. Conventional optical coatings largely rely on physical vapor deposition (PVD) methods like evaporation, where the coating layer is formed by vaporizing the source material and then condensing it onto the intended substrate. In contrast, ALD and ALE rely on a cyclic series of self-limiting chemical reactions that result in the deposition (or removal) of material one atomic layer at a time. This self-limiting characteristic results in a coating or etchings that are conformal over arbitrary shapes with precisely controlled layer thickness determined by the number of ALD or ALE cycles performed.
The ALD and ALE techniques are common in the semiconductor industry where they are used to fabricate high-performance transistors. Their use as an optical coating method is less common, particularly at ultraviolet wavelengths where the choice of optical coating material is largely restricted to metal fluorides instead of more common metal oxides, due to the larger optical band energy of fluoride materials, which minimizes absorption losses in the coatings. Using an approach based on co-reaction with hydrogen fluoride, the team at JPL has developed a variety of fluoride-based ALD and ALE processes.
(left) The Supernova remnants and Proxies for ReIonization Testbed Experiment (SPRITE) CubeSat primary mirror inside the ALD coating facility at JPL, the mirror is 18 cm on the long and is the largest optic coated in this chamber to-date. (right) Flight optic coating inside JPL ALD chamber for Pioneers Aspera Mission. Like SPRITE, the Aspera coating combines a lithium fluoride process developed at NASA GSFC with thin ALD encapsulation of magnesium fluoride at JPL. Image Credit: NASA-JPL In addition to these metal-fluoride materials, layers of aluminum are often used to construct structures like reflective mirrors and bandpass filters for instruments operating in the UV. Although aluminum has high intrinsic UV reflectance, it also readily forms a surface oxide that strongly absorbs UV light. The role of the metal fluoride coating is then to protect the aluminum surface from oxidation while maintaining enough transparency to create a mirror with high reflectance.
The use of ALD in this context has initially been pursued in the development of telescope optics for two SmallSat astrophysics missions that will operate in the UV: the Supernova remnants and Proxies for ReIonization Testbed Experiment (SPRITE) CubeSat mission led by Brian Fleming at the University of Colorado Boulder, and the Aspera mission led by Carlos Vargas at the University of Arizona. The mirrors for SPRITE and Aspera have reflective coatings that utilize aluminum protected by lithium fluoride using a novel PVD processes developed at NASA Goddard Space Flight Center, and an additional very thin top coating of magnesium fluoride deposited via ALD.
Team member John Hennessy prepares to load a sample wafer in the ALD coating chamber at JPL. Image Credit: NASA JPL The use of lithium fluoride enables SPRITE and Aspera to “see” further into the UV than other missions like NASA’s Hubble Space Telescope, which uses only magnesium fluoride to protect its aluminum mirror surfaces. However, a drawback of lithium fluoride is its sensitivity to moisture, which in some cases can cause the performance of these mirror coatings to degrade on the ground prior to launch. To circumvent this issue, very thin layers (~1.5 nanometers) of magnesium fluoride were deposited by ALD on top of the lithium fluoride on the SPRITE and Aspera mirrors. The magnesium fluoride layers are thin enough to not strongly impact the performance of the mirror at the shortest wavelengths, but thick enough to enhance the stability against humidity during ground phases of the missions. Similar approaches are being considered for the mirror coatings of the future NASA flagship Habitable Worlds Observatory (HWO).
Multilayer structures of aluminum and metal fluorides can also function as bandpass filters (filters that allow only signals within a selected range of wavelengths to pass through to be recorded) in the UV. Here, ALD is an attractive option due to the inherent repeatability and precise thickness control of the process. There is currently no suitable ALD process to deposit aluminum, and so additional work by the JPL team has explored the development of a custom vacuum coating chamber that combines the PVD aluminum and ALD fluoride processes described above. This system has been used to develop UV bandpass filters that can be deposited directly onto imaging sensors like silicon (Si) CCDs. These coatings can enable such sensors to operate with high UV efficiency, but low sensitivity to longer wavelength visible photons that would otherwise add background noise to the UV observations.
Structures composed of multilayer aluminum and metal fluoride coatings have recently been delivered as part of a UV camera to the Star-Planet Activity Research CubeSat (SPARCS) mission led by Evgenya Shkolnik at Arizona State University. The JPL-developed camera incorporates a delta-doped Si CCD with the ALD/PVD filter coating on the far ultraviolet channel, yielding a sensor with high efficiency in a band centered near 160 nm with low response to out-of-band light.
A prototype of a back-illuminated CCD incorporating a multi-layer metal-dielectric bandpass filter coating deposited by a combination of thermal evaporation and ALD. This coating combined with JPL back surface passivation approaches enable the Si CCD to operate with high UV efficiency while rejecting longer wavelength light. Image credit: NASA JPL Next, the JPL team that developed these coating processes plans to focus on implementing a similar bandpass filter on an array of larger-format Si Complementary Metal-Oxide-Semiconductor (CMOS) sensors for the recently selected NASA Medium-Class Explorer (MIDEX) UltraViolet EXplorer (UVEX) mission led by Fiona Harrison at the California Institute of Technology, which is targeted to launch in the early 2030s.
For additional details, see the entry for this project on NASA TechPort
Project Lead: Dr. John Hennessy, Jet Propulsion Laboratory (JPL)
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Last Updated Mar 18, 2025 Related Terms
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By NASA
Students, mentors, and team supporters donning team colors watch robots clash on the playing field at the FIRST Robotics Los Angeles regional competition in El Segundo on March 16. NASA/JPL-Caltech Robots built by high schoolers vied for points in a fast-moving game inspired by complex ocean ecosystems at the FIRST Robotics Los Angeles regional competition.
High school students who spent weeks designing, assembling, and testing 125-pound rolling robots put their fast-moving creations into the ring over the weekend, facing off at the annual Los Angeles regional FIRST Robotics Competition, an event supported by NASA’s Jet Propulsion Laboratory in Southern California.
Four of the 43 participating teams earned a chance to compete in April at the FIRST international championship tournament in Houston, which draws winning teams from across the country.
Held March 14 to 16 at the Da Vinci Schools campus in El Segundo, the event is one of many supported by the nonprofit FIRST (For Inspiration and Recognition of Science and Technology), which pairs students with STEM professionals. Teams receive the game rules, which change every year, in January and sprint toward competition, assembling their robot based on FIRST’s specifications. The global competition not only gives students engineering experience but also helps them develop business skills with a range of activities, from fundraising for their team to marketing.
For this year’s game, called “Reefscape,” two alliances of three teams competed for points during each 2½-minute match. That meant six robots at a time sped across the floor, knocking into each other and angling to seed “coral” (pieces of PVC pipe) on “reefs” and harvesting “algae” (rubber balls). In the final seconds of each round, teams could earn extra points if their robots were able to hoist themselves into the air and dangle from hanging cages, as though they were ascending to the ocean surface.
The action was set to a bouncy soundtrack that reverberated through the gym, while in the bleachers there were choreographed dancing, loud cheers, pom-poms, and even some tears.
The winning alliance was composed of Warbots from Downey’s Warren High School, TorBots from Torrance’s South High School, and West Torrance Robotics from Torrance’s West High School. The Robo-Nerds of Benjamin Franklin High in Los Angeles’ Highland Park and Robo’Lyon from Notre Dame de Bellegarde outside Lyon, France, won awards that mean they’ll also get to compete in Houston, alongside the Warbots and the TorBots.
NASA and its Robotics Alliance Project provide grants for high school teams across the country and support FIRST Robotics competitions to encourage students to pursue STEM careers in aerospace. For the L.A. regional competition, JPL has coordinated volunteers — and provided coaching and mentoring to teams, judges, and other competition support — for 25 years.
For more information about the FIRST Los Angeles regional, visit:
https://cafirst.org/frc/losangeles/
News Media Contact
Melissa Pamer
Jet Propulsion Laboratory, Pasadena, Calif.
626-314-4928
melissa.pamer@jpl.nasa.gov
2025-037
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Last Updated Mar 17, 2025 Related Terms
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Explore This Section Webb News Latest News Latest Images Blog (offsite) Awards X (offsite – login reqd) Instagram (offsite – login reqd) Facebook (offsite- login reqd) Youtube (offsite) Overview About Who is James Webb? Fact Sheet Impacts+Benefits FAQ Science Overview and Goals Early Universe Galaxies Over Time Star Lifecycle Other Worlds Observatory Overview Launch Deployment Orbit Mirrors Sunshield Instrument: NIRCam Instrument: MIRI Instrument: NIRSpec Instrument: FGS/NIRISS Optical Telescope Element Backplane Spacecraft Bus Instrument Module Multimedia About Webb Images Images Videos What is Webb Observing? 3d Webb in 3d Solar System Podcasts Webb Image Sonifications Team International Team People Of Webb More For the Media For Scientists For Educators For Fun/Learning 5 Min Read NASA’s Webb Images Young, Giant Exoplanets, Detects Carbon Dioxide
NASA’s James Webb Space Telescope has provided the clearest look in the infrared yet at the iconic multi-planet system HR 8799. Full image below. Credits:
NASA, ESA, CSA, STScI, W. Balmer (JHU), L. Pueyo (STScI), M. Perrin (STScI) NASA’s James Webb Space Telescope has captured direct images of multiple gas giant planets within an iconic planetary system. HR 8799, a young system 130 light-years away, has long been a key target for planet formation studies.
The observations indicate that the well-studied planets of HR 8799 are rich in carbon dioxide gas. This provides strong evidence that the system’s four giant planets formed much like Jupiter and Saturn, by slowly building solid cores that attract gas from within a protoplanetary disk, a process known as core accretion.
The results also confirm that Webb can infer the chemistry of exoplanet atmospheres through imaging. This technique complements Webb’s powerful spectroscopic instruments, which can resolve the atmospheric composition.
“By spotting these strong carbon dioxide features, we have shown there is a sizable fraction of heavier elements, like carbon, oxygen, and iron, in these planets’ atmospheres,” said William Balmer, of Johns Hopkins University in Baltimore. “Given what we know about the star they orbit, that likely indicates they formed via core accretion, which is an exciting conclusion for planets that we can directly see.”
Balmer is the lead author of the study announcing the results published today in The Astrophysical Journal. Balmer and their team’s analysis also includes Webb’s observation of a system 97 light-years away called 51 Eridani.
Image A: HR 8799 (NIRCam Image)
NASA’s James Webb Space Telescope has provided the clearest look in the infrared yet at the iconic multi-planet system HR 8799. The closest planet to the star, HR 8799 e, orbits 1.5 billion miles from its star, which in our solar system would be located between the orbit of Saturn and Neptune. The furthest, HR 8799 b, orbits around 6.3 billion miles from the star, more than twice Neptune’s orbital distance. Colors are applied to filters from Webb’s NIRCam (Near-Infrared Camera), revealing their intrinsic differences. A star symbol marks the location of the host star HR 8799, whose light has been blocked by the coronagraph. In this image, the color blue is assigned to 4.1 micron light, green to 4.3 micron light, and red to the 4.6 micron light. NASA, ESA, CSA, STScI, W. Balmer (JHU), L. Pueyo (STScI), M. Perrin (STScI) Image B: 51 Eridani (NIRCam Image)
Webb’s NIRCam (Near-Infrared Camera) captured this image of 51 Eridani b (also referred to as 51 Eri b), a cool, young exoplanet that orbits 890 million miles from its star, similar to Saturn’s orbit in our solar system. The 51 Eridani system is 97 light-years from Earth. This image includes filters representing 4.1-micron light as red. The background red in this image is not light from other planets, but a result of light subtraction during image processing. NASA, ESA, CSA, STScI, W. Balmer (JHU), L. Pueyo (STScI), M. Perrin (STScI) HR 8799 is a young system about 30 million years old, a fraction of our solar system’s 4.6 billion years. Still hot from their tumultuous formation, the planets within HR 8799 emit large amounts of infrared light that give scientists valuable data on how they formed.
Giant planets can take shape in two ways: by slowly building solid cores with heavier elements that attract gas, just like the giants in our solar system, or when particles of gas rapidly coalesce into massive objects from a young star’s cooling disk, which is made mostly of the same kind of material as the star. The first process is called core accretion, and the second is called disk instability. Knowing which formation model is more common can give scientists clues to distinguish between the types of planets they find in other systems.
“Our hope with this kind of research is to understand our own solar system, life, and ourselves in the comparison to other exoplanetary systems, so we can contextualize our existence,” Balmer said. “We want to take pictures of other solar systems and see how they’re similar or different when compared to ours. From there, we can try to get a sense of how weird our solar system really is—or how normal.”
Image C: Young Gas Giant HR 8799 e (NIRCam Spectrum)
This graph shows a spectrum of one of the planets in the HR 8799 system, HR 8799 e. Spectral fingerprints of carbon dioxide and carbon monoxide appear in data collected by Webb’s NIRCam (Near-Infrared Camera). NASA, ESA, CSA, STScI, J. Olmsted (STScI) Of the nearly 6,000 exoplanets discovered, few have been directly imaged, as even giant planets are many thousands of times fainter than their stars. The images of HR 8799 and 51 Eridani were made possible by Webb’s NIRCam (Near-Infrared Camera) coronagraph, which blocks light from bright stars to reveal otherwise hidden worlds.
This technology allowed the team to look for infrared light emitted by the planets in wavelengths that are absorbed by specific gases. The team found that the four HR 8799 planets contain more heavy elements than previously thought.
The team is paving the way for more detailed observations to determine whether objects they see orbiting other stars are truly giant planets or objects such as brown dwarfs, which form like stars but don’t accumulate enough mass to ignite nuclear fusion.
“We have other lines of evidence that hint at these four HR 8799 planets forming using this bottom-up approach” said Laurent Pueyo, an astronomer at the Space Telescope Science Institute in Baltimore, who co-led the work. “How common is this for planets we can directly image? We don’t know yet, but we’re proposing more Webb observations to answer that question.”
“We knew Webb could measure colors of the outer planets in directly imaged systems,” added Rémi Soummer, director of STScI’s Russell B. Makidon Optics Lab and former lead for Webb coronagraph operations. “We have been waiting for 10 years to confirm that our finely tuned operations of the telescope would also allow us to access the inner planets. Now the results are in and we can do interesting science with it.”
The NIRCam observations of HR 8799 and 51 Eridani were conducted as part of Guaranteed Time Observations programs 1194 and 1412 respectively.
The James Webb Space Telescope is the world’s premier space science observatory. Webb will solve mysteries in our solar system, look beyond to distant worlds around other stars, and probe the mysterious structures and origins of our universe and our place in it. Webb is an international program led by NASA with its partners, ESA (European Space Agency) and the Canadian Space Agency.
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Media Contacts
Laura Betz – laura.e.betz@nasa.gov
NASA’s Goddard Space Flight Center, Greenbelt, Md.
Hannah Braun – hbraun@stsci.edu
Space Telescope Science Institute, Baltimore, Md.
Roberto Molar Candanosa
Johns Hopkins University, Baltimore, Md.
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By USH
EBANI stands for "Unidentified Anomalous Biological Entity," referring to a mysterious class of airborne phenomena that may be biological rather than mechanical in nature. These entities are often described as elongated, flexible, and tubular, moving through the sky in a serpentine or twisting manner.
They exhibit advanced flight capabilities, including high-speed travel, precise control, and even self-illumination. Some have been observed rendering themselves invisible, raising questions about their energy sources and possible technological origins.
Recent observations have revealed formations of translucent spheres in red, white, and blue, challenging conventional classifications of both biology and aerodynamics.
Some of these entities have a massive structure composed of thousands of clustered spheres. These entities appear to function as an aircraft carrier, releasing these smaller spheres into Earth's atmosphere for an unknown purpose.
While some researchers propose that EBANIs are natural organisms evolving in Earth's upper atmosphere under unfamiliar physical laws, others speculate they may be advanced artificial (eventually biological) constructs, potentially extraterrestrial probes or surveillance devices, given the presence of large structures expelling numerous smaller spheres.
Are they living UFOs, advanced biological organisms that function autonomously within the spheres, without the need for pilots?
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By European Space Agency
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