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Webb Detects Tiny Quartz Crystals in the Clouds of a Hot Gas Giant


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Webb Detects Tiny Quartz Crystals in the Clouds of a Hot Gas Giant

Researchers using NASA’s James Webb Space Telescope have detected evidence for quartz nanocrystals in the high-altitude clouds of WASP-17 b, a hot Jupiter exoplanet 1,300 light-years from Earth. The detection, which was uniquely possible with MIRI (Webb’s Mid-Infrared Instrument), marks the first time that silica (SiO2) particles have been spotted in an exoplanet atmosphere.

Illustration showing a portion of the disk of a cloudy planet set against the black background of space. About one-eighth of the planet is visible. It fills the lower right half of the frame, with the limb (the edge, or horizon) curving from the bottom left corner to the upper right corner. The planet is partially lit by a star that is off to the upper left, out of view. The planet is brightest along the limb (on the dayside), and grows dimmer toward the lower right corner (the nightside), becoming almost completely dark about halfway in. Wispy, light-tan-colored clouds are visible in the lit portion and there is a hazy blueish glow along the horizon. Several stars are scattered in the background.
This artist concept shows what the exoplanet WASP-17 b could look like.
Graphics: NASA, ESA, CSA, and R. Crawfor, d (STScI)Science: Nikole Lewis (Cornell University), David Grant (University of Bristol), Hannah Wakeford (University of Bristol) Crawford (STScI)

“We were thrilled!” said David Grant, a researcher at the University of Bristol in the UK and first author on a paper being published today in the Astrophysical Journal Letters. “We knew from Hubble observations that there must be aerosols—tiny particles making up clouds or haze—in WASP-17 b’s atmosphere, but we didn’t expect them to be made of quartz.”

Silicates (minerals rich in silicon and oxygen) make up the bulk of Earth and the Moon as well as other rocky objects in our solar system, and are extremely common across the galaxy. But the silicate grains previously detected in the atmospheres of exoplanets and brown dwarfs appear to be made of magnesium-rich silicates like olivine and pyroxene, not quartz alone – which is pure SiO2.


The result from this team, which also includes researchers from NASA’s Ames Research Center and NASA’s Goddard Space Flight Center, puts a new spin on our understanding of how exoplanet clouds form and evolve. “We fully expected to see magnesium silicates,” said co-author Hannah Wakeford, also from the University of Bristol. “But what we’re seeing instead are likely the building blocks of those, the tiny ‘seed’ particles needed to form the larger silicate grains we detect in cooler exoplanets and brown dwarfs.”

Detecting Subtle Variations


With a volume more than seven times that of Jupiter and a mass less than one-half Jupiter, WASP-17 b is one of the largest and puffiest known exoplanets. This, along with its short orbital period of just 3.7 Earth-days, makes the planet ideal for transmission spectroscopy : a technique that involves measuring the filtering and scattering effects of a planet’s atmosphere on starlight.


Webb observed the WASP-17 system for nearly 10 hours, collecting more than 1,275 brightness measurements of 5- to 12-micron mid-infrared light as the planet crossed its star. By subtracting the brightness of individual wavelengths of light that reached the telescope when the planet was in front of the star from those of the star on its own, the team was able to calculate the amount of each wavelength blocked by the planet’s atmosphere.


What emerged was an unexpected “bump” at 8.6 microns, a feature that would not be expected if the clouds were made of magnesium silicates or other possible high temperature aerosols like aluminum oxide, but which makes perfect sense if they are made of quartz.

alt="Graphic titled “Hot Gas Giant Exoplanet WASP-17 b Composition of Cloud Particles, MIRI Low-Resolution Time-Series Spectroscopy” showing 28 data points plotted as white circles with vertical error bars on a graph of amount of light blocked in percent on the y-axis versus wavelength of light in microns on the x-axis. The y-axis ranges from 1.45 to 1.65 percent. The x-axis ranges from 5 to 12 microns. A jagged purple line is labeled “Model spectrum based on Webb, Hubble, and Spitzer data.” One broad, prominent peak visible in the data and model is highlighted with a vertical green band labeled “Light blocked by quartz (S I O 2) crystals.” The peak is centered at about 8.6 microns and 1.59 percent. Running across the green band below the purple peak, is a jagged dashed yellow line labeled “What the spectrum would look like with no quartz clouds.” This line slopes down to the right. In the background is an illustration of a planet with wispy clouds and a hazy blueish glow along the horizon."
A transmission spectrum of the hot gas giant exoplanet WASP-17 b captured by Webb’s Mid-Infrared Instrument (MIRI) on March 12-13, 2023, reveals the first evidence for quartz (crystalline silica, SiO2) in the clouds of an exoplanet. The spectrum was made by measuring the change in brightness of 28 wavelength-bands of mid-infrared light as the planet transited the star. Webb observed the WASP-17 system using MIRI’s low-resolution spectrograph for nearly 10 hours, collecting more than 1,275 measurements before, during, and after the transit. For each wavelength, the amount of light blocked by the planet’s atmosphere (white circles) was calculated by subtracting the amount that made it through the atmosphere from the amount originally emitted by the star. The solid purple line is a best-fit model to the Webb (MIRI), Hubble, and Spitzer data. (The Hubble and Spitzer data cover wavelengths from 0.34 to 4.5 microns and are not shown on the graph.) The spectrum shows a clear feature around 8.6 microns, which astronomers think is caused by silica particles absorbing some of the starlight passing through the atmosphere. The dashed yellow line shows what that part of the transmission spectrum would look like if the clouds in WASP-17 b’s atmosphere did not contain SiO2. This marks the first time that SiO2 has been identified in an exoplanet, and the first time any specific cloud species has been identified in a transiting exoplanet.
Graphics: NASA, ESA, CSA, and R. Crawfor, d (STScI)Science: Nikole Lewis (Cornell University), David Grant (University of Bristol), Hannah Wakeford (University of Bristol) Crawford (STScI)

Download full resolution images for this article from the Space Telescope Science Institute (STScI)

Crystals, Clouds, and Winds


While these crystals are probably similar in shape to the pointy hexagonal prisms found in geodes and gem shops on Earth, each one is only about 10 nanometers across—one-millionth of one centimeter.


“Hubble data actually played a key role in constraining the size of these particles,” explained co-author Nikole Lewis of Cornell University, who leads the Webb Guaranteed Time Observation (GTO) program designed to help build a three-dimensional view of a hot Jupiter atmosphere. “We know there is silica from Webb’s MIRI data alone, but we needed the visible and near-infrared observations from Hubble for context, to figure out how large the crystals are.”


Unlike mineral particles found in clouds on Earth, the quartz crystals detected in the clouds of WASP-17 b are not swept up from a rocky surface. Instead, they originate in the atmosphere itself. “WASP-17 b is extremely hot—around 1,500 degrees Celsius (2,700°F)—and the pressure where they form high in the atmosphere is only about one-thousandth of what we experience on Earth’s surface,” explained Grant. “In these conditions, solid crystals can form directly from gas, without going through a liquid phase first.”


Understanding what the clouds are made of is crucial for understanding the planet as a whole. Hot Jupiters like WASP-17 b are made primarily of hydrogen and helium, with small amounts of other gases like water vapor (H2O) and carbon dioxide (CO2). “If we only consider the oxygen that is in these gases, and neglect to include all of the oxygen locked up in minerals like quartz (SiO2), we will significantly underestimate the total abundance,” explained Wakeford. “These beautiful silica crystals tell us about the inventory of different materials and how they all come together to shape the environment of this planet.”


Exactly how much quartz there is, and how pervasive the clouds are, is hard to determine. “The clouds are likely present along the day/night transition (the terminator), which is the region that our observations probe,” said Grant. Given that the planet is tidally locked with a very hot day side and cooler night side, it is likely that the clouds circulate around the planet, but vaporize when they reach the hotter day side. “The winds could be moving these tiny glassy particles around at thousands of miles per hour.”


WASP-17 b is one of three planets targeted by the JWST-Telescope Scientist Team’s Deep Reconnaissance of Exoplanet Atmospheres using Multi-instrument Spectroscopy (DREAMS) investigations, which are designed to gather a comprehensive set of observations of one representative from each key class of exoplanets: a hot Jupiter, a warm Neptune, and a temperate rocky planet. The MIRI observations of hot Jupiter WASP-17 b were made as part of GTO program 1353.


The James Webb Space Telescope is the world’s premier space science observatory. Webb is solving mysteries in our solar system, looking beyond to distant worlds around other stars, and probing the mysterious structures and origins of our universe and our place in it. Webb is an international program led by NASA with its partners, ESA (European Space Agency) and the Canadian Space Agency.

Media Contacts:

Laura Betz
NASA’s Goddard Space Flight Center, Greenbelt, Md.
laura.e.betz@nasa.gov

Christine Pulliam
Space Telescope Science Institute, Baltimore, Md.
cpulliam@stsci.edu

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      Image A: Artist’s Concept of TOI-421 b
      This artist’s concept shows what the hot sub-Neptune exoplanet TOI-421 b could look like. It is based on spectroscopic data gathered by Webb, as well as previous observations from other telescopes on the ground and in space. Illustration: NASA, ESA, CSA, Dani Player (STScI) Small, Cool, Shrouded in Haze
      The existence of sub-Neptunes was unexpected before they were discovered by NASA’s retired Kepler space telescope in the last decade. Now, astronomers are trying to understand where these planets came from and why are they so common.
      Before Webb, scientists had very little information on them. While sub-Neptunes are a few times larger than Earth, they are still much smaller than gas-giant planets and typically cooler than hot Jupiters, making them much more challenging to observe than their gas-giant counterparts.
      A key finding prior to Webb was that most sub-Neptune atmospheres had flat or featureless transmission spectra. This means that when scientists observed the spectrum of the planet as it passed in front of its host star, instead of seeing spectral features – the chemical fingerprints that would reveal the composition of the atmosphere – they saw only a flat-line spectrum. Astronomers concluded from all of those flat-line spectra that at least certain sub-Neptunes were probably very highly obscured by either clouds or hazes.
      Image B: Spectrum of TOI-421 b
      A transmission spectrum captured by NASA’s James Webb Space Telescope reveals chemicals in the atmosphere of the hot sub-Neptune exoplanet TOI-421 b. Illustration: NASA, ESA, CSA, Joseph Olmsted (STScI) A Different Kind of Sub-Neptune?
      “Why did we observe this planet, TOI-421 b? It’s because we thought that maybe it wouldn’t have hazes,” said Kempton. “And the reason is that there were some previous data that implied that maybe planets over a certain temperature range were less enshrouded by haze or clouds than others.”
      That temperature threshold is about 1,070 degrees Fahrenheit. Below that, scientists hypothesized that a complex set of photochemical reactions would occur between sunlight and methane gas, and that would trigger the haze. But hotter planets shouldn’t have methane and therefore perhaps shouldn’t have haze.
      The temperature of TOI-421 b is about 1,340 degrees Fahrenheit, well above the presumed threshold. Without haze or clouds, researchers expected to see a clear atmosphere – and they did!
      A Surprising Finding
      “We saw spectral features that we attribute to various gases, and that allowed us to determine the composition of the atmosphere,” said the University of Maryland’s Brian Davenport, a third-year Ph.D. student who conducted the primary data analysis. “Whereas with many of the other sub-Neptunes that had been previously observed, we know their atmospheres are made of something, but they’re being blocked by haze.”
      The team found water vapor in the planet’s atmosphere, as well as tentative signatures of carbon monoxide and sulfur dioxide. Then there are molecules they didn’t detect, such as methane and carbon dioxide. From the data, they can also infer that a large amount of hydrogen is in TOI-421 b’s atmosphere.
      The lightweight hydrogen atmosphere was the big surprise to the researchers. “We had recently wrapped our mind around the idea that those first few sub-Neptunes observed by Webb had heavy-molecule atmospheres, so that had become our expectation, and then we found the opposite,” said Kempton. This suggests TOI-421 b may have formed and evolved differently from the cooler sub-Neptunes observed previously.
      Is TOI-421 b Unique?
      The hydrogen-dominated atmosphere is also interesting because it mimics the composition of TOI-421 b’s host star. “If you just took the same gas that made the host star, plopped it on top of a planet’s atmosphere, and put it at the much cooler temperature of this planet, you would get the same combination of gases. That process is more in line with the giant planets in our solar system, and it is different from other sub-Neptunes that have been observed with Webb so far,” said Kempton.
      Aside from being hotter than other sub-Neptunes previously observed with Webb, TOI-421 b orbits a Sun-like star. Most of the other sub-Neptunes that have been observed so far orbit smaller, cooler stars called red dwarfs.
      Is TOI-421b emblematic of hot sub-Neptunes orbiting Sun-like stars, or is it just that exoplanets are very diverse? To find out, the researchers would like to observe more hot sub-Neptunes to determine if this is a unique case or a broader trend. They hope to gain insights into the formation and evolution of these common exoplanets.
      “We’ve unlocked a new way to look at these sub-Neptunes,” said Davenport. “These high-temperature planets are amenable to characterization. So by looking at sub-Neptunes of this temperature, we’re perhaps more likely to accelerate our ability to learn about these planets.”
      The team’s findings appear on May 5 in the Astrophysical Journal Letters.
      The James Webb Space Telescope is the world’s premier space science observatory. Webb is solving mysteries in our solar system, looking beyond to distant worlds around other stars, and probing the mysterious structures and origins of our universe and our place in it. Webb is an international program led by NASA with its partners, ESA (European Space Agency) and CSA (Canadian Space Agency).
      To learn more about Webb, visit:
      https://science.nasa.gov/webb
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      Media Contacts
      Laura Betz – laura.e.betz@nasa.gov
      NASA’s Goddard Space Flight Center, Greenbelt, Md.
      Ann Jenkins – jenkins@stsci.edu
      Space Telescope Science Institute, Baltimore, Md.
      Hannah Braun – hbraun@stsci.edu
      Space Telescope Science Institute, Baltimore, Md.
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      Last Updated May 04, 2025 Editor Marty McCoy Contact Laura Betz laura.e.betz@nasa.gov Related Terms
      James Webb Space Telescope (JWST) Astrophysics Exoplanets Goddard Space Flight Center Science & Research The Universe View the full article
    • By NASA
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      Help Classify Galaxies Seen by NASA’s James Webb Space Telescope!
      The Galaxy Zoo classification interface shows you an image from NASA’s Webb telescope and asks you questions about it. Image credit: Galaxy Zoo, Zooniverse. Inset galaxy: NASA/STScI/CEERS/TACC/S. Finkelstein/M. Bagley/Z. Levay/A. Pagan NASA needs your help identifying the shapes of thousands of galaxies in images taken by our James Webb Space Telescope with the Galaxy Zoo project. These classifications will help scientists answer questions about how the shapes of galaxies have changed over time, what caused these changes, and why. Thanks to the light collecting power of Webb, there are now over 500,000 images of galaxies on website of the Galaxy Zoo citizen science project—more images than scientists can classify by themselves. 
      “This is a great opportunity to see images from the newest space telescope,” said volunteer Christine Macmillan from Aberdeen, Scotland. “Galaxies at the edge of our universe are being seen for the first time, just as they are starting to form. Just sign up and answer simple questions about the shape of the galaxy that you are seeing. Anyone can do it, ages 10 and up!”  
      As we look at more distant objects in the universe, we see them as they were billions of years ago because light takes time to travel to us. With Webb, we can spot galaxies at greater distances than ever before. We’re seeing what some of the earliest galaxies ever detected look like, for the first time. The shapes of these galaxies tell us about how they were born, how and when they formed stars, and how they interacted with their neighbors. By looking at how more distant galaxies have different shapes than close galaxies, we can work out which processes were more common at different times in the universe’s history.   
      At Galaxy Zoo, you’ll first examine an image from the Webb telescope. Then you will be asked several questions, such as ‘Is the galaxy round?’, or ‘Are there signs of spiral arms?’. If you’re quick, you may even be the first person to see the galaxies you’re asked to classify.  
      “I’m amazed and honored to be one of the first people to actually see these images! What a privilege!” said volunteer Elisabeth Baeten from Leuven, Belgium.
      Galaxy Zoo is a citizen science project with a long history of scientific impact. Galaxy Zoo volunteers have been exploring deep space since July 2007, starting with a million galaxies from a telescope in New Mexico called the Sloan Digital Sky Survey and then, moving on to images from space telescopes like NASA’s Hubble Space Telescope and ESA (European Space Agency)’s Euclid telescope. The project has revealed spectacular mergers, taught us about how the black holes at the center of galaxies affect their hosts, and provided insight into how features like spiral arms form and grow.  
      Now, in addition to adding new data from Webb, the science team has incorporated an AI algorithm called ZooBot, which will sift through the images first and label the ‘easier ones’ where there are many examples that already exist in previous images from the Hubble Space Telescope. When ZooBot is not confident on the classification of a galaxy, perhaps due to complex or faint structures, it will show it to users on Galaxy Zoo to get their human classifications, which will then help ZooBot learn more. Working together, humans and AI can accurately classify limitless numbers of galaxies. The Galaxy Zoo science team acknowledges support from the International Space Sciences Institute (ISSI), who provided funding for the team to get together and work on Galaxy Zoo. Join the project now.  
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      Last Updated Apr 29, 2025 Related Terms
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